SMZI

A game-changing zero valent iron technology

S-MicroZVI® is an advanced zero-valent iron (ZVI) product proven to accomplish In Situ Chemical Reduction (ISCR) of contaminants within the subsurface environment and is also used for the immobilisation of hexavalent chromium.

S-MicroZVI is manufactured using a state-of-the-art sulfidation process resulting in a particle coating which increases activation toward specific contaminants and extends performance longevity. S-MicroZVI destroys contaminants abiotically and is applied to stimulate ISCR-enhanced bioremediation.


What is it?

S-MicroZVI is delivered as a colloidal suspension 40% ZVI by weight in glycerol with a particle size of less than 5 microns. S-MicroZVI is manufactured using a state-of-the-art sulfidation process resulting in a particle coating which increases activation toward specific contaminants and extends performance longevity. S-MicroZVI destroys contaminants abiotically and is applied to stimulate ISCR-enhanced bioremediation.

How it works

The micro scale (colloidal) particles flow through soil pores dispersing outward without the need for fracturing or mechanical mixing in the subsurface. The particle size and the sulfidation helps create an anoxic and highly reducing environment, providing ideal conditions for sequential enhanced anaerobic biodegradation to destroy chlorinated contaminants.


Benefits

  • Easy to apply – suspended in a colloidal solution, the product allows for easy handling and application on-site
  • Disperse widely in the subsurface aquifers
  • Excellent reactivity
  • Extended longevity – outperforming commodity iron by 30-40 times
  • Treats a wide range of contaminants

Target Contaminants

  • Chlorinated solvents
  • Haloalkanes
  • Pesticides
  • Herbicides
  • Energetics
  • Hexavalent Chromium, Cr(VI)

For a complete overview of contaminants treatable with S-MicroZVI, please see our Range of Treatable Contaminant Guide and our Treatment Applicability Overview

S-MicroZVI particle

Illustration shown is a representation of a zero valent iron particle. S-Micro ZVI particles are milled down to less than 5 microns for best results.



RESOURCES

Technical Bulletin: Benefits of Sulfidation

sulfidated zvi

Case Studies



About In Situ Chemical Reduction (ISCR)

S-MicroZVI and other ZVI products are used in soil and groundwater remediation as an in situ chemical reduction (ISCR) reagents. Chemical reduction is the process of adding or donating electrons to contaminants, while chemical oxidation is the process of removing or accepting electrons from contaminants. The ZVI acts as a reducing agent to provide electrons directly to the contaminant for degradation or to support processes that require electrons to degrade contaminants.

Abiotic Degradation
Zero-valent iron can provide an abiotic degradation pathway involving the direct reaction of ZVI with groundwater contaminants. The abiotic, “beta-elimination pathway” for chlorinated ethenes is shown in the bottom of Figure 1. The abiotic pathway involves short-lived dichloroacetylene and chloroacetylene intermediates, bypasses the formation cDCE and VC, and ultimately results in ethene and ethane.

 

Figure 1

 

Figure 1: ISCR or beta-elimination (double-line arrows). Beta-elimination avoids the formation of cDCE and VC.

Biological Degradation
Biological degradation involves the destruction of contaminants by anaerobic bacteria that are supported by the molecular hydrogen that is produced by the fermentation of organic hydrogen donors or by the reaction of ZVI with water. The biological degradation pathway for perchloroethene (PCE) and trichloroethene (TCE) is provided in Figure 2. This pathway, called reductive dechlorination (or hydrogenolysis), involves the sequential replacement of a chlorine atom with a hydrogen atom and is always accompanied by the formation cis-1,2-dichloroethene (cDCE) and vinyl chloride (VC). Many common anaerobic bacteria can transform PCE to TCE and then to cDCE, but only Dehalococcoides ethenogenes (DHC) can transform cDCE and VC to ethene.

 

Figure 2

 

Figure 2: Reductive dechlorination sequentially replaces chlorine atoms with hydrogen atoms. The intermediates cDCE and VC are more toxic than parent compounds PCE and TCE.

Supplementing dechlorinating bacteria with zero-valent iron and organic hydrogen donors can enable more rapid and complete biodegradation. Zero-valent iron quickly deoxygenates groundwater and provides an electrochemically reducing environment that is highly fertile for the microbes involved in anaerobic bioremediation. In many situations this favorable environment can be sustained for several years.

ISCR-Enhanced Bioremediation
ISCR-enhanced bioremediation is a term describing the remediation approach that combines zero-valent iron (ZVI), an organic hydrogen donor, and contaminant-degrading microbes (native or bioaugmented) in order to degrade contaminants in soil and groundwater. This approach is most commonly used for chlorinated contaminants, e.g. chlorinated ethenes. ISCR-enhanced bioremediation is particularly effective because it stimulates anaerobic biological degradation by rapidly creating a reducing environment favorable to reductive dichlorination. Furthermore, ISCR-enhanced bioremediation may limit the formation of undesirable daughter products such as cDCE and VC by degrading parent compounds via direct chemical reduction.

ISCR-enhanced bioremediation can be used to treat contaminants such as chlorinated solvents, haloalkanes, and chlorinated pesticides. Contaminants that are resistant to abiotic degradation (e.g. 1,2-dichloroethane or dichloromethane) and compounds that can inhibit bioremediation (e.g. 1,1,1-trichloroethane or chloroform) may be effectively treated by ISCR-enhanced bioremediation. ISCR-enhanced bioremediation can be used for source zones, plumes, and barrier applications.

About S-MicroZVI

S-MicroZVI is a suspension of sulfidated, colloidal zero-valent iron (ZVI) that promotes the destruction of many organic pollutants, including chlorinated solvents, pesticides, haloalkanes and energetics. It is engineered to promote multiple pathways for contaminant degradation which leads to faster cleanup while minimizing daughter product formation. In addition, S-MicroZVI is easy to handle and simple to inject leading to significantly better reagent distribution.

In many cases this improved formulation of ZVI can also destroy contaminants through a direct chemical reaction as shown in Figure 3.

 

Figure 1

Figure 3. Example of chlorinated ethene degradation pathways and products. The top line with single-line arrows represents the reductive dechlorination (hydrogenolysis) pathway. The downward facing double-arrows represent the abiotic beta-elimination pathway.

S-MicroZVI is composed of colloidal, sulfidated zero-valent iron (ZVI) particles suspended in an aqueous medium with environmentally-acceptable, proprietary dispersants. The passivation technique of sulfidation, completed through proprietary processing methods, provides unparalleled reactivity with chlorinated hydrocarbons like PCE and TCE, and increases its stability and longevity in situ by minimizing undesirable side-reactions.

In addition to superior reactivity, S-MicroZVI is designed for easy handling that is unmatched by any ZVI material on the market. Shipped as an suspension in glycerol, S-MicroZVI requires no powder feeders, no thickening with guar, and pneumatic or hydraulic fracturing is not mandatory. When diluted with water in the field, the resulting suspension is easy to mix and inject using direct push or injections wells.

Application Approach
S-MicroZVI is diluted with water on site and easily applied into the subsurface through low-pressure injections. S-MicroZVI can also be mixed with products like 3-D Microemulsion or PlumeStop prior to injection. For more information, please read the S-MicroZVI Application Instructions.

7 Reasons to Consider ISCR to Treat Your Site

This ebook outlines the benefits of in situ chemical reduction (ISCR), an approach that can be highly effective when designing a remedial strategy. Though in situ chemical reduction has been in use for some time, recent technological advances have improved it as a remedial approach.

Technical Bulletin: ISCR-Enhanced Bioremediation

iscr enhanced bioremediation

In Situ Chemical Reduction (ISCR) enhanced bioremediation combines zero valent iron (ZVI), an organic hydrogen donor and contaminant-degrading microbes to degrade contaminants in soil and groundwater.  It is particularly effective because it rapidly creates a reducing environment favourable to reductive dechlorination. Furthermore, ISCR-enhanced bioremediation may limit the formation of toxic daughter products

Frequently Asked Questions

ZVI FAQs

The following frequently asked questions about zero-valent iron are taken from a webinar given by John Freim PhD, ZVI Product Manager and Director of Materials Science at REGENESIS. A recording of this webinar is available online and can be accessed in full here.

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